Chiral Photochemistry / Edition 1

by Yoshihisa Inoue, V. Ramamurthy

Overview

Control of molecular chirality is central to contemporary chemistry, biology, and materials-related areas. Chiral photochemistry employs molecular and supramolecular chiral interactions in the electronically excited state to induce molecular chirality, providing new and versatile strategies and surprising results unattainable by conventional thermal asymmetric synthesis. Chiral Photochemistry is the first book devoted solely to this rapidly growing area. This comprehensive and authoritative book covers all aspects of the subject, from circularly polarized light to supramolecular chiral source and from the origin of homochirality in the biosphere to chiral devices and materials.

Product Details

ISBN-13:	9780367393939
Publisher:	Taylor & Francis
Publication date:	06/19/2019
Pages:	704
Product dimensions:	6.00(w) x 9.00(h) x (d)

About the Author

Yoshihisa Inoue, V. Ramamurthy

Table of Contents

Preface iii

Contributors vii

1 Direct Asymmetric Photochemistry with Circularly Polarized Light Hermann Rau 1

2 Coherent Laser Control of the Handedness of Chiral Molecules Paul Brumer Moske Shapiro 45

3 Magnetochiral Anisotropy in Asymmetric Photochemistry G. L. J. A. Rikken 107

4 Enantiodifferentiating Photosensitized Reactions Yoshihisa Inoue 129

5 Diastereodifferentiating Photoreactions Norbert Hoffmann Jean-Pierre Pete 179

6 Chirality in Photochromism Yasushi Yokoyama Masako Saito 235

7 Chiral Photochemistry with Transition Metal Complexes Shigeyoshi Sakaki Taisuke Hamada 261

8 Template-Induced Enantioselective Photochemical Reactions in Solution Benjamin Grosch Thorsten Bach 315

9 Supramolecular Asymmetric Photoreactions Takehiko Wada Yoshihisa Inoue 341

10 Circular Dichroism in the Solid State Reiko Kuroda 385

11 Absolute Asymmetric Photochemistry Using Spontaneous Chiral Crystallization Masami Sakamoto 415

12 The Solid-State Ionic Chiral Auxiliary Approach to Asymmetric Induction in Photochemical Reactions John R. Scheffer 463

13 Chiral Solid-State Photochemistry Including Supramolecular Approaches Hideko Koshima 485

14 Racemic-to-Chiral Transformation and the Chirality Inversion Process in Cobaloxime Complex Crystals Only by Photoirradiation Yuji Ohashi 533

15 Chiral Photochemistry Within Zeolites V. Ramamurthy J. Sivaguru J. Shailaja Arunkumar Natarajan Lakshmi S. Kaanumalle S. Karthikeyan Abraham Joy 563

16 Photochemistry of Chiral Polymers Eiji Yashima 633

Index 667