High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes: A Study of Molecular and Electronic Structure

Carola Vogel’s PhD thesis focuses on the synthesis, and structural and spectroscopic characterization of the first high valent iron nitride complexes. In her interdisciplinary and collaborative research Carola also describes the reactivity studies of a unique iron (V) nitride complex with water. These studies show that quantitative yields of ammonia are given at ambient conditions. High valent iron nitride and oxo species have been proposed as key intermediates in many bio-catalytic transformations, but until now these species have proven exceedingly challenging to isolate and study. Iron complexes in high oxidation states can thus serve as models for iron-containing enzymes to help us understand biological systems or aid our development of more efficient industrial catalysts.

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High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes: A Study of Molecular and Electronic Structure

Carola Vogel’s PhD thesis focuses on the synthesis, and structural and spectroscopic characterization of the first high valent iron nitride complexes. In her interdisciplinary and collaborative research Carola also describes the reactivity studies of a unique iron (V) nitride complex with water. These studies show that quantitative yields of ammonia are given at ambient conditions. High valent iron nitride and oxo species have been proposed as key intermediates in many bio-catalytic transformations, but until now these species have proven exceedingly challenging to isolate and study. Iron complexes in high oxidation states can thus serve as models for iron-containing enzymes to help us understand biological systems or aid our development of more efficient industrial catalysts.

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High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes: A Study of Molecular and Electronic Structure

High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes: A Study of Molecular and Electronic Structure

by Carola S. Vogel
High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes: A Study of Molecular and Electronic Structure

High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes: A Study of Molecular and Electronic Structure

by Carola S. Vogel

eBook2012 (2012)

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Overview

Carola Vogel’s PhD thesis focuses on the synthesis, and structural and spectroscopic characterization of the first high valent iron nitride complexes. In her interdisciplinary and collaborative research Carola also describes the reactivity studies of a unique iron (V) nitride complex with water. These studies show that quantitative yields of ammonia are given at ambient conditions. High valent iron nitride and oxo species have been proposed as key intermediates in many bio-catalytic transformations, but until now these species have proven exceedingly challenging to isolate and study. Iron complexes in high oxidation states can thus serve as models for iron-containing enzymes to help us understand biological systems or aid our development of more efficient industrial catalysts.


Product Details

ISBN-13: 9783642272547
Publisher: Springer-Verlag New York, LLC
Publication date: 02/03/2012
Series: Springer Theses
Sold by: Barnes & Noble
Format: eBook
Pages: 132
File size: 3 MB

Table of Contents

-Chapter 1: Introduction to Tripodal N-Heterocyclic Carbene Iron Complexes.- Chapter 2: TIMENmes − An Iron Nitride Complex. -Chapter 3: TIMENtol/3,5xyl Unexpected Reactivity Resulting from Modifications of the
Ligand Periphery. -Chapter 4: TIMEN3,5CF3 Hybrid System Capable of Cyclometallation and Nitride
Insertion. -Chapter 5: PhB(tBuIm)3 Synthesis, Structure, and Reactivity of an Iron(V) Nitride. -Chapter 6: PhB(MesIm)3 Spin Crossover in a Four-Coordinate Iron(II) Complex.
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