Noble Metal Noble Value: Ru-, Rh-, Pd-catalyzed Heterocycle Synthesis

by Xiao-feng Wu (Editor)

Overview

Heterocyclic chemistry constitutes the largest branch of chemistry, covering almost two-thirds of literature in the field. In addition, around 90% of naturally-occurring molecules have heterocycles as their core structure. Therefore, as a central part of organic chemistry, the discovery of new methodologies in synthesizing heterocyclic compounds is essential to their continued application and development. Transition metal catalysts offer a low cost and often low toxicity pathway for heterocycles synthesis, while the use of noble metals represents an alternative form of experimentation which is discussed in the book.Noble Metals, Noble Value provides the first comprehensive analysis of the applications of the noble metals of ruthenium (Ru), rhodium (Rh) and palladium (Pd) catalysts in heterocycles synthesis. Pairs of chapters are dedicated to summarizing each of the metals when applied to either five- or six-membered heterocyclic syntheses. An introduction to the importance of heterocycles and possible procedures for the preparation of heterocyclic compounds is also given.With up to date research and findings, this review is excellently suited to academics and professionals in the field of chemistry, with a particular focus on the specialities of biological, catalytic and organic chemistry.

Product Details

ISBN-13:	9781783269235
Publisher:	Imperial College Press
Publication date:	08/29/2016
Series:	Catalytic Science Series , #15
Pages:	392
Product dimensions:	5.90(w) x 9.10(h) x 1.00(d)

Table of Contents

Acknowledgments vii

Chapter 1 Ru-Catalyzed Five-Membered Heterocycles Synthesis 1

Chapter 2 Ruthenium Catalysis in the Synthesis of Six-Membered Heterocycles 75

Chapter 3 Rh-Catalyzed Five-Membered Heterocycle Synthesis 127

Chapter 4 Rh-Catalyzed Six-Membered Heterocycles Synthesis 173

Chapter 5 Palladium-Catalyzed Synthesis of Five-Membered Heterocycles 249

Chapter 6 Pd-Catalyzed Six-Membered Heterocycles Synthesis 283

Chapter 7 Pd-Catalyzed Synthesis of Sulfur- and Phosphorus-Containing Heterocycles via G-H Activation 335

Chapter 8 Pd-Catalyzed Heterocycle Synthesis in Ionic Liquids 351

Index 369