Physical Chemistry: A Molecular Approach / Edition 1

by Donald A. McQuarrie, John D. Simon

Overview

As the first modern physical chemistry textbook to cover quantum mechanics before thermodynamics and kinetics, this book provides a contemporary approach to the study of physical chemistry. By beginning with quantum chemistry, students will learn the fundamental principles upon which all modern physical chemistry is built. The text includes a special set of “MathChapters” to review and summarize the mathematical tools required to master the material Thermodynamics is simultaneously taught from a bulk and microscopic viewpoint that enables the student to understand how bulk properties of materials are related to the properties of individual constituent molecules. This new text includes a variety of modern research topics in physical chemistry as well as hundreds of worked problems and examples.Translated into French, Italian, Japanese, Spanish and Polish.

Product Details

ISBN-13:	9780935702996
Publisher:	University Science Books
Publication date:	08/20/1997
Edition description:	1997
Pages:	1360
Product dimensions:	7.00(w) x 10.25(h) x (d)

About the Author

As the author of landmark chemistry books and textbooks, Donald McQuarrie's name is synonymous with excellence in chemical education. From his classic text on Statistical Mechanics to his recent quantum-first tour de force on Physical Chemistry, McQuarrie's best selling textbooks are highly acclaimed by the chemistry community. McQuarrie received his PhD from the University of Oregon, and is Professor Emeritus from the Department of Chemistry at the University of California, Davis.

John D. Simon became the first George B. Geller Professor of Chemistry at Duke University in 1998. He is currently Chair Chemistry Department at Duke and a faculty member of the Biochemistry, and Ophthalmology Departments of the Duke Medical Center. John graduated from Williams College in 1979 with a B.A. in Chemistry and received his Ph.D. from Harvard University in 1983. After a postdoctoral fellowship with Professor Mostafa El-Sayed at UCLA, John joined the faculty of the Department of Chemistry at UCSD in 1985.

Table of Contents

CONTENTSPreface1.The Dawn of Quantum TheoryMath Chapter A/Complex Numbers2. The Classical Wave EquationMath Chapter B/Probability and Statistics3. The Schrodinger Equation and a Particle In a BoxMath Chapter C/ Vectors4. Some Postulates and General Principles of Quantum MechanicsMath Chapter D/ Spherical Coordinates5. The Harmonic Oscillator and the Rigid Rotator: Two Spectroscopic Models6. The Hydrogen AtomMath Chapter E/ Determinants7. Approximation Methods8. Multielectron Atoms9. The Chemical Bond: Diatomic Molecules10. Bonding in Polyatomic Molecules11. Computational Quantum ChemistryMath Chapter F/ Matrices12. Group Theory: The Exploitation of Symmetry13. Molecular Spectroscopy14. Nuclear Magnetic Resonance Spectroscopy15. Lasers, Laser Spectroscopy, and PhotochemistryMath Chapter G/Numerical Methods16. The Properties of GasesMath Chapter H/Partial Derivatives17. The Boltzmann Factor and Partition FunctionsMath Chapter I/Series and Limits18. Partition Functions and Ideal Gases19. The First Law of ThermodynamicsMath Chapter J/ The Binomial Distribution and Stirling's Approximation20. Entropy and the Second Law of Thermodynamics21. Entropy and the Third Law of Thermodynamics22. Helmholtz and Gibbs Energies23. Phase Equilibria24. Solutions I: Liquid-Liquid Solutions25. Solutions II: Solid-Liquid Solutions26. Chemical Equilibria27. The Kinetic Theory of Gases28. Chemical Kinetics I: Rate Laws29. Chemical Kinetics II: Reaction Mechanisms30. Gas-Phase Reaction Dynamics31. Solids and Surface Chemistry-Answers to Numerical Problems-Index

Editorial Reviews

It is a superb book, to be greatly appreciated and treasured by generations of students to come. My congratulations to the authors for a task so well executed. All of us who labor to teach the dreaded P. Chem. course are in your debt.

Richard Zare

It is beautifully produced, with clear diagrams and nice touches, such as the short biographies of scientists that appear between chapters…(McQuarrie and Simon) set high standards and many of us, as teachers and professionals in physical chemistry, will find inspiration in, and have our aspirations raised by, this text.

The Times Higher

McQuarrie and Simon approach physical chemistry in a fashion different from most other books. The approach is pedagogically pleasing, as it builds up physical chemistry from considerations of atoms to systems containing numerous molecules.

Choice

McQuarrie and Simon have developed an excellent modern physical chemistry course that should inspire us to rethink our curriculum.

Journal of Chemical Education

In the undergraduate quantum course here at Princeton, we use your physical chemistry textbook, which many of us affectionately call “Big Red.” I don’t think that most people expect a lot out of a physical chemistry book, except maybe to be confused. Your book, however, I found to be truly outstanding. It is both a thorough and exceptionally clear presentation of physical chemistry concepts. I have friends in the physics department who survived their very rigorous quantum courses by relying on your book because they couldn’t understand the one used in the physics class.

Benjamin Goldstein

A true double thumbs up! Throughout my entire undergraduate study, both thermodynamic and reaction kinetics were conducted in a very classical manner. Whereas most of the advanced courses, thermo. and reaction kinetics, conducted here in CMU are basically dealing with all kinds of microscopic phenomena. Your book has served as a very good platform to link up my previous experiences with my current study.

Lim Jit Kang

Emphasizes a molecular approach to physical chemistry, discussing principles of quantum mechanics first and then using those ideas in development of thermodynamics and kinetics. Chapters on quantum subjects are interspersed with ten math chapters reviewing mathematical topics used in subsequent chapters. Includes material on current physical chemical research, with chapters on computational quantum chemistry, group theory, NMR spectroscopy, and lasers. Units and symbols used in the text follow IUPAC recommendations. Includes exercises. Annotation c. by Book News, Inc., Portland, Or.

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